But there is one problem with connecting batteries in series, and this is that batteries are not electrically identical. They have slight differences in internal resistance. So, when a series string of batteries is charged, this difference in resistance will cause a variance in terminal voltages on each battery. Their voltages become “unbalanced”.
When creating a lead-acid battery bank with a higher voltage, like 24 or 48V you will need to connect multiple 12V batteries in series. But there is one problem with connecting batteries in series, and this is that batteries are not electrically identical. They have slight differences in internal resistance.
The number of batteries you can wire in series, parallel, or series-parallel depends on the specific application and the capabilities of the battery bank you are building. For details, refer to the user manual of the specific battery or contact the battery manufacturer if necessary.
To wire multiple batteries in series, connect the negative terminal (-) of one battery to the positive terminal (+) of another, and do the same to the rest. Take Renogy 12V 200Ah Core Series LiFePO4 Battery as an example. You can connect up to 4 such batteries in series. In this system, the system voltage and current are calculated as follows:
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